Phosphorus trichloride is a colorless to pale yellow transparent liquid with a pungent and foul odor. It is volatile, highly corrosive and toxic. It is prone to hydrolysis in moist air, generating hydrogen chloride fumes. It decomposes to produce toxic gases when exposed to open flames or high temperatures. As an important intermediate in organic synthesis and chemical production, it possesses strong reducibility.
Physical & Chemical Properties
Molecular FormulaPCl3
Density:1.6g/cm³g/cm³
Boiling Point:76℃
Solubility:
It is readily soluble in organic solvents such as benzene, ether, chloroform and carbon disulfide; it reacts violently with water to produce phosphoric acid and hydrogen chloride (resulting in white fumes), and is insoluble in cold water (hydrolysis will occur).
Molecular Weight:137.35g/mol
Flash Point:
Melting Point:-112℃
Uses
1. Organic synthesis: Used as a chlorinating agent and catalyst for the synthesis of phosphoryl chloride, phosphite esters and organophosphorus pesticides (trichlorfon, dimethoate, etc.).
2. Chemical raw materials: For the production of phosphoric acid, phosphorus oxychloride, phosphorous acid, flame retardants, plasticizers, etc.
3. Pharmaceutical field: For the synthesis of pharmaceutical intermediates (antibiotics, anti-tuberculosis drugs, etc.).
4. Others: Used as semiconductor dopant, raw material for dye synthesis and metal surface treatment agent.
Safety, Security & Risk
Physical Hazards
Vapor is heavier than air.
Chemical Hazards
When heated, it decomposes to generate toxic and corrosive fumes containing hydrogen chloride and phosphorus oxides. It reacts with oxidizing agents. It reacts violently with water, generating heat and decomposition products including hydrochloric acid and phosphoric acid, which presents fire and explosion hazards. It also reacts violently with alcohols, phenols and alkalis, and corrodes metals and many other materials.