Thionyl chloride is a colorless to pale yellow transparent liquid with a strong pungent and suffocating odor. It emits fumes in moist air. It is chemically reactive and serves as a highly effective chlorinating agent and acyl chlorinating agent. It reacts violently with water, alcohols, amines, etc., releasing hydrogen chloride and sulfur dioxide gases.
Physical & Chemical Properties
Molecular FormulaSOCl2
Density:1.64g/cm³g/cm³
Boiling Point: 76℃
Solubility:
Insoluble in water; freely soluble in organic solvents such as benzene, carbon tetrachloride, chloroform and diethyl ether.
Molecular Weight:118.97g/mol
Flash Point:
Melting Point:-104.5℃
Uses
1. Organic Synthesis:Converts carboxylic acids to acyl chlorides and alcohols to alkyl chlorides. It is a key chlorinating reagent for the synthesis of pharmaceutical, pesticide and dye intermediates.
2. Lithium Battery Industry:Used in the preparation of lithium salts (e.g. LiFSI, LiPF₆) and electrolyte additives.
3. Others:Used as a dehydrating agent and chlorinating agent in polymers, fragrances, metal surface treatment and other fields.
Safety, Security & Risk
Physical Hazards
Vapors are heavier than air.
Chemical Hazards
May decompose above 140 °C, producing toxic and corrosive fumes.Reacts violently with water, forming toxic fumes of sulfur dioxide and hydrogen chloride.Reacts with many substances, including combustible materials, amines, alkalis and metals, with risk of fire and explosion.